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Journal Articles

Chemical properties of rutherfordium (Rf) and dubnium (Db) in the aqueous phase

Nagame, Yuichiro; Kratz, J. V.*; Sch$"a$del, M.*

EPJ Web of Conferences, 131, p.07007_1 - 07007_8, 2016/12

BB2016-0022.pdf:0.96MB

 Times Cited Count:3 Percentile:72.98(Chemistry, Inorganic & Nuclear)

Journal Articles

First ionization potential of the heaviest actinide lawrencium, element 103

Sato, Tetsuya; Asai, Masato; Borschevsky, A.*; Stora, T.*; Sato, Nozomi*; Kaneya, Yusuke; Tsukada, Kazuaki; D$"u$llmann, C. E.*; Eberhardt, K.*; Eliav, E.*; et al.

EPJ Web of Conferences, 131, p.05001_1 - 05001_6, 2016/12

 Times Cited Count:0 Percentile:0.9(Chemistry, Inorganic & Nuclear)

Ionization efficiency in a surface ionization process depends on the first ionization potential of the atom. Based on the dependence, the ionization potential of the atom can be determined. We measured ionization efficiencies of fermium, einsteinium, mendelevium, and lawrencium by using a newly developed gas-jet coupled surface ion-source. The ionization potential of the elements have not been determined so far due to their low production rates and/or their short half-lives. Based on a relationship between the ionization efficiency and the ionization potential obtained via measurements of short-lived lanthanide isotopes, the ionization potentials of these actinide elements have been successfully determined.

Journal Articles

Stability and synthesis of superheavy elements; Fighting the battle against fission - Example of $$^{254}$$No

Lopez-Martens, A.*; Henning, G.*; Khoo, T. L.*; Seweryniak, D.*; Alcorta, M.*; Asai, Masato; Back, B. B.*; Bertone, P. F.*; Boilley, D.*; Carpenter, M. P.*; et al.

EPJ Web of Conferences, 131, p.03001_1 - 03001_6, 2016/12

 Times Cited Count:1 Percentile:43.94(Chemistry, Inorganic & Nuclear)

Fission barrier height and its angular-momentum dependence have been measured for the first time in the nucleus with the atomic number greater than 100. The entry distribution method, which can determine the excitation energy at which fission starts to dominate the decay process, was applied to $$^{254}$$No. The fission barrier of $$^{254}$$No was found to be 6.6 MeV at zero spin, indicating that the $$^{254}$$No is strongly stabilized by the nuclear shell effects.

Journal Articles

Complex chemistry with complex compounds

Eichler, R.*; Asai, Masato; Brand, H.*; Chiera, N. M.*; Di Nitto, A.*; Dressler, R.*; D$"u$llmann, Ch. E.*; Even, J.*; Fangli, F.*; Goetz, M.*; et al.

EPJ Web of Conferences, 131, p.07005_1 - 07005_7, 2016/12

 Times Cited Count:3 Percentile:72.98(Chemistry, Inorganic & Nuclear)

In recent years gas-phase chemical studies assisted by physical pre-separation allowed for the productions and investigations of fragile single molecular species of superheavy elements. The latest highlight is the formation of very volatile hexacarbonyl compound of element 106, Sg(CO)$$_{6}$$. Following this success, second-generation experiments were performed to measure the first bond dissociation energy between the central metal atom and the surrounding ligand. The method using a tubular decomposition reactor was developed and successfully applied to short-lived Mo(CO)$$_{6}$$, W(CO)$$_{6}$$, and Sg(CO)$$_{6}$$.

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